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Efficient synthesis of EDOT modified ABBB-type unsymmetrical zinc phthalocyanine: Optoelectrochromic and glucose sensing properties of its copolymerized film

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dc.contributor.author Göktuǧ, O.
dc.contributor.author Soganci, T.
dc.contributor.author Ak, M.
dc.contributor.author Kasim Şener, M.
dc.date.accessioned 2019-08-16T12:59:07Z
dc.date.available 2019-08-16T12:59:07Z
dc.date.issued 2017
dc.identifier.issn 11440546 (ISSN)
dc.identifier.uri http://acikerisim.pau.edu.tr:8080/xmlui/handle/11499/9242
dc.description.abstract A new unsymmetrical zinc(ii) phthalocyanine (ZnPc2) bearing one EDOT group was efficiently synthesized as a monomer through the statistical condensation reaction. The other products of mixed cyclotetramerization ZnPc1, ZnPc3 and ZnPc4 were also isolated. Obtained ZnPc2 is a good precursor for the synthesis of new functional linear electropolymers. This was approved by the successful electrochemical copolymerization reaction between ZnPc2 and SNS type monomer HKCN in which the amino group was desired for the enzyme immobilization. The electrochromic and glucose sensing properties of copolymer P(ZnPc2-co-HKCN) obtained by electrochemical oxidative polymerization were investigated. Based on spectroelectrochemical studies, the P(ZnPc2-co-HKCN) copolymer showed a greenish yellow colour in the reduced state and a dark blue colour in the oxidized state as a film. An optical contrast ratio of 44% at 471 nm was achieved with a fast switching time (2.5 s). Meanwhile, the novel biosensor constructed from P(ZnPc2-co-HKCN) showed a linear amperometric response to glucose within a concentration range of 0.1 mM to 1.5 mM (LOD: 0.049 mM). These data illustrate the possible use of the P(ZnPc2-co-HKCN) modified electrode as an amperometric glucose sensor. © 2017 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
dc.language.iso English
dc.publisher Royal Society of Chemistry
dc.relation.isversionof 10.1039/c7nj03250a
dc.subject 3,4 (ethylenedioxy)thiophene
dc.subject copolymer
dc.subject glucose
dc.subject monomer
dc.subject phthalocyanine zinc
dc.subject thiophene derivative
dc.subject unclassified drug
dc.subject Article
dc.subject chemical structure
dc.subject color
dc.subject contrast
dc.subject cyclic potentiometry
dc.subject electrochemical detection
dc.subject enzyme immobilization
dc.subject infrared spectroscopy
dc.subject matrix assisted laser desorption ionization time of flight mass spectrometry
dc.subject polymerization
dc.subject priority journal
dc.subject proton nuclear magnetic resonance
dc.subject synthesis
dc.subject thin layer chromatography
dc.subject ultraviolet spectroscopy
dc.title Efficient synthesis of EDOT modified ABBB-type unsymmetrical zinc phthalocyanine: Optoelectrochromic and glucose sensing properties of its copolymerized film
dc.type Article
dc.relation.journal New Journal of Chemistry
dc.identifier.volume 41
dc.identifier.issue 23
dc.identifier.startpage 14080
dc.identifier.endpage 14087
dc.identifier.index Scopus

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