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Synthesis and characterization of a novel quinoxaline-substituted vic-dioxime and its complexes containing bis(12-diazacrown-4) derivatives

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dc.contributor.author Bilgin, A.
dc.contributor.author Ertem, B.
dc.contributor.author Gök, Yaşar.
dc.date.accessioned 2019-08-16T11:32:15Z
dc.date.available 2019-08-16T11:32:15Z
dc.date.issued 2007
dc.identifier.issn 00092673 (ISSN)
dc.identifier.uri http://acikerisim.pau.edu.tr:8080/xmlui/handle/11499/4102
dc.description.abstract A new quinoxaline-substituted vicinal dioxime ligand containing bis( 12-diazacrown-4) units (H2L) was synthesized by the reaction of cyanogen di-N-oxide with compound 4. Mononuclear NiII and Cu II complexes with a metal: ligand ratio of 1:2 for H2L and a trinuclear CuII complex were also synthesized. The mononuclear CuII species coordinated to two CuII ions through the deprotonated oximate oxygens to yield a trinuclear structure cis-bridged by the ox-imate groups, with 1,10-phenanthroline as an end-cap ligand. The mononuclear CoIII complex of H2L was isolated with pyridine and chlorine as axial ligands. In addition, a CoIII complex containing the BF2+ bridge macrocycle was synthesized using a precursor hydrogen-bridged CoIII complex via a template effect. The extraction abilities of 1, 3, and 11 were also evaluated in 1,2-dichloroethane by using several alkali (Li+, Na+, K+, and Cs+) and transition-metal picrates, such as Ag+, Pb 2+, Cd2+, Cu2+, and Zn2+. Structures of the ligands and metal complexes were solved by elemental analyses, 1H and 13CNMR, FT-IR, UV-vis, and mass spectra. © 2007 The Chemical Society of Japan.
dc.language.iso English
dc.relation.isversionof 10.1246/bcsj.80.1549
dc.rights info:eu-repo/semantics/closedAccess
dc.subject Cesium
dc.subject Chelation
dc.subject Chlorine
dc.subject Chlorine compounds
dc.subject Coordination reactions
dc.subject Hydrogen
dc.subject Ligands
dc.subject Mass spectrometry
dc.subject Metal complexes
dc.subject Metal recovery
dc.subject Metallic compounds
dc.subject Oxygen
dc.subject Synthesis (chemical)
dc.subject Transition metals
dc.subject Zinc
dc.subject Axial ligands
dc.subject Complexes containing
dc.subject Dichloro ethanes
dc.subject Dioxime
dc.subject Elemental analyses
dc.subject Extraction abilities
dc.subject Macrocycle
dc.subject Metal:ligand ratios
dc.subject Phenanthroline
dc.subject Quinoxaline
dc.subject Synthesis and characterizations
dc.subject Template effects
dc.subject Trinuclear structures
dc.subject Cobalt compounds
dc.title Synthesis and characterization of a novel quinoxaline-substituted vic-dioxime and its complexes containing bis(12-diazacrown-4) derivatives
dc.type Article
dc.relation.journal Bulletin of the Chemical Society of Japan
dc.identifier.volume 80
dc.identifier.issue 8
dc.identifier.startpage 1549
dc.identifier.endpage 1555
dc.relation.publicationCategory Uluslararası Hakemli Dergi
dc.identifier.index Scopus
dc.identifier.index WOS


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