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Optoelectrochromic characterization and smart windows application of bi-functional amid substituted thienyl pyrrole derivative

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dc.contributor.author Soganci, Tugba
dc.contributor.author Soyleyici, Sevil
dc.contributor.author Soyleyici, Hakan Can
dc.contributor.author Ak, Metin
dc.date.accessioned 2019-07-12T06:20:57Z
dc.date.available 2019-07-12T06:20:57Z
dc.date.issued 2017-06-02
dc.identifier.issn 0032-3861
dc.identifier.uri https://hdl.handle.net/11499/3990
dc.description.abstract Because of some disadvantages of polythiophenes and polypyrroles, alternatively thienylpyrrole monomers which include these two heterocycles in its structure have been synthesized for overcome optical, electrical and stability problems. However, the desired properties can only be achieved by the copolymerization of thienylpyrroles with EDOT. The optical, electrical properties and stability of the thienylpyrrole compounds have reached unique levels when using amide substituent derivatives synthesized by our group for the first time. In this work, terephthalamide was used to synthesize double-sided, symmetric amide substituted thienyl pyrrole. By doing so, we obtained a superstructure that provides three dimensional electrical conductivity and has much better optical, electrical properties and stability. Besides investigation of its optical and electrical properties, deposition of the polymer film on the electrode during electropolymerization and the ion mobility in the redox process were determined by EQCM. An electrochromic device has been constructed with this new type polymer to demonstrate the utility of its use in practical applications. As a result, it has been shown that the new type amide substituted thienyl pyrrole derivatives have promising usage for all practical applications of conductive polymers due to their unique properties such as high optical contrast, high stability and fast response time. en_US
dc.language.iso en en_US
dc.publisher Elsevier B.V. en_US
dc.relation.ispartof Polymer en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.subject Dithienylpyrrole en_US
dc.subject Polythiophenes en_US
dc.subject Polypyrroles en_US
dc.subject 2,5-di(2-thienyl)pyrrole en_US
dc.subject PEDOT en_US
dc.subject EQCM en_US
dc.subject QCM en_US
dc.subject Conducting polymers en_US
dc.subject Cyclic voltammetry en_US
dc.subject Mass sensor en_US
dc.subject Electrochromic materials en_US
dc.subject Coloration efficiencies en_US
dc.subject Smart windows en_US
dc.subject Electrochromic devices en_US
dc.title Optoelectrochromic characterization and smart windows application of bi-functional amid substituted thienyl pyrrole derivative en_US
dc.type Article en_US
dc.identifier.volume 118 en_US
dc.identifier.startpage 40 en_US
dc.identifier.endpage 48 en_US
dc.authorid 0000-0003-1906-9115
dc.authorid 0000-0003-1906-9115
dc.authorid 0000-0002-0000-4613
dc.relation.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
dc.identifier.wos WOS:000403744500005 en_US
dc.baslikedit $$başlıkdublike$$

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