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An eco-friendly method to enhance optical and electrical properties of conducting polymers by means of carboxymethyl cellulose

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dc.contributor.author Ak, Metin
dc.contributor.author Soğancı, Tuğba
dc.date.accessioned 2019-07-11T10:44:43Z
dc.date.available 2019-07-11T10:44:43Z
dc.date.issued 2019-03-15
dc.identifier.issn 0969-0239
dc.identifier.uri http://hdl.handle.net/11499/3931
dc.description.abstract In this work, an eco-friendly method is proposed for the electro-synthesis of conductive polymers with superior optical and electrical properties by means of CMC in aqueous media. For this purpose, an aqueous dispersion of a water-insoluble monomer namely 4-amino-N-[2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl]benzamide (TPB) has been prepared by attaching it to CMC via hydrogen bonds and the conductive composite film (PTPB–CMC) has been obtained by electropolymerization. The TPB monomer has been chosen to interact with the CMC via hydrogen bonds which ensures to obtain dispersion with the CMC and also increase the compatibility of its polymer in the composite structure. As a result of the electrochemical, spectroelectrochemical investigation and surface morphology analyses of the obtained conductive polymer, it has been found that anionic CMC makes improvements in the electrical, optical and mechanical properties of the polymer by making the plasticizing effect and acting as a dopant. Furthermore, in the presence of nanocarbon materials on electrode surface, it has been determined that the polymerization potential is reduced and more stable and long-lasting polymeric films which are crucial for technological applications have been obtained. tr_TR
dc.language.iso en tr_TR
dc.publisher Springer Nature tr_TR
dc.rights info:eu-repo/semantics/closedAccess tr_TR
dc.subject Conducting polymers tr_TR
dc.subject Green synthesis tr_TR
dc.subject Cellulose tr_TR
dc.subject Complexation tr_TR
dc.subject Composite films tr_TR
dc.subject Composite materials tr_TR
dc.subject Dispersions tr_TR
dc.subject Electrochemistry tr_TR
dc.subject Electrochromic materials tr_TR
dc.subject Spectroscopic analysis tr_TR
dc.subject Cyclic voltammetry tr_TR
dc.subject Electrodes tr_TR
dc.subject Electropolymerization tr_TR
dc.subject Environmental protection tr_TR
dc.subject Mechanical properties tr_TR
dc.subject Monomers tr_TR
dc.subject Spectroelectrochemistry tr_TR
dc.subject Carboxymethyl cellulose tr_TR
dc.subject Conductive composites tr_TR
dc.subject Optical and electrical properties tr_TR
dc.subject Mechanical properties tr_TR
dc.subject Polymerization potential tr_TR
dc.subject Spectroelectrochemical investigations tr_TR
dc.subject Surface morphology analysis tr_TR
dc.subject Thienylpyrroles tr_TR
dc.subject 2,5-di(2-thienyl)pyrrole tr_TR
dc.title An eco-friendly method to enhance optical and electrical properties of conducting polymers by means of carboxymethyl cellulose tr_TR
dc.type article tr_TR
dc.relation.journal Cellulose tr_TR
dc.contributor.authorID https://orcid.org/0000-0002-0000-4613 tr_TR
dc.identifier.volume 26 tr_TR
dc.identifier.issue 4 tr_TR
dc.identifier.startpage 2541 tr_TR
dc.identifier.endpage 2555 tr_TR
dc.relation.publicationCategory Uluslararası Hakemli Dergi
dc.identifier.index Scopus
dc.identifier.index WOS

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