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Electrochemistry of secondary amine substituted 2,5-di(2-thienyl)pyrrole derivative and its copolymer

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dc.contributor.author Ak, Metin
dc.contributor.author Gumusay, Ogun
dc.contributor.author Soyleyici, Hakan Can
dc.contributor.author Soganci, Tugba
dc.contributor.author Cetisli, Halil
dc.date.accessioned 2019-07-11T07:15:32Z
dc.date.available 2019-07-11T07:15:32Z
dc.date.issued 2017-05-03
dc.identifier.issn 0013-4651
dc.identifier.uri http://hdl.handle.net/11499/3899
dc.description.abstract Since the discovery of conductive polymers, one of the most promising innovations in the field of polymer chemistry, these materials have been used in many practical applications. However, new monomers are being designed to overcome some of the disadvantages of conductive polymers, such as their inherent stability, low optical and electrical properties. It is known that minor arrangement on the monomer structure lead to very large changes in the polymer properties. In this study, a thienyl pyrrole monomer, one of the most studied monomers in the field of conductive polymers, has been produced using hydrazine derivatives instead of amines. For this purpose, the model monomer, N-phenyl-2,5-di(thiophen-2-yl)-1H-pyrrol-1-amine, was synthesized and the optical, electrochemical and electrochromic properties of its conductive polymer were investigated. Furthermore, copolymer studies with 3,4-ethylenedioxythiophene (EDOT) have been done to emphasize the importance of copolymerization on electrochromic properties of the conducting polymers. Effects of the feed ratio of the monomers and applied potential for copolymerization on optical and electrochemical properties of the electrochemically synthesized copolymers were investigated in detail. tr_TR
dc.language.iso en tr_TR
dc.publisher Electrochemical Society, Inc. tr_TR
dc.rights info:eu-repo/semantics/closedAccess tr_TR
dc.subject Electrochemistry tr_TR
dc.subject Conducting polymers tr_TR
dc.subject Spectroscopic analysis tr_TR
dc.subject Electrochromic materials tr_TR
dc.subject Synthesis tr_TR
dc.subject Electrochromic devices tr_TR
dc.subject Cyclic voltammetry tr_TR
dc.subject Coloration efficiencies tr_TR
dc.subject Copolymerization tr_TR
dc.subject Electrochromism tr_TR
dc.subject 2,5-di(2-thienyl)pyrrole tr_TR
dc.subject PEDOT tr_TR
dc.subject Electrochromic properties tr_TR
dc.subject Hydrazine derivatives tr_TR
dc.subject Monomer structures tr_TR
dc.subject Optical and electrical properties tr_TR
dc.subject Polymer properties tr_TR
dc.subject Pyrrole derivatives tr_TR
dc.subject Polythiophenes tr_TR
dc.subject Feed ratio tr_TR
dc.subject Copolymer compositions tr_TR
dc.title Electrochemistry of secondary amine substituted 2,5-di(2-thienyl)pyrrole derivative and its copolymer tr_TR
dc.type article tr_TR
dc.relation.journal Journal of the Electrochemical Society tr_TR
dc.contributor.authorID https://orcid.org/0000-0002-0000-4613 tr_TR
dc.contributor.authorID https://orcid.org/0000-0002-9601-2238
dc.contributor.authorID https://orcid.org/0000-0001-6258-2577
dc.contributor.authorID https://orcid.org/0000-0003-1906-9115
dc.contributor.authorID https://orcid.org/0000-0003-2091-4267
dc.identifier.volume 164 tr_TR
dc.identifier.issue 7 tr_TR
dc.identifier.startpage H421 tr_TR
dc.identifier.endpage H429 tr_TR
dc.relation.publicationCategory Uluslararası Hakemli Dergi
dc.identifier.index Scopus
dc.identifier.index WOS

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