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Ferrocenyl dithiophosphonate functionalized inorganic-organic hybrid conductive polymer with green color in neutral state

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dc.contributor.author Koyundereli Çılgı, Gülbanu
dc.contributor.author Karakuş, Mehmet
dc.contributor.author Ak, Metin
dc.date.accessioned 2019-07-09T05:52:46Z
dc.date.available 2019-07-09T05:52:46Z
dc.date.issued 2013-09
dc.identifier.issn 0379-6779
dc.identifier.uri https://hdl.handle.net/11499/3766
dc.identifier.uri https://doi.org/10.1016/j.synthmet.2013.07.017
dc.description.abstract We report the synthesis and the characterization of the first electroactive ferrocenyl dithiophosphonate functionalized inorganic-organic hybrid conductive polymer. Electropolymerization was realized in boron trifluoride diethyl etherate (BFEE) with an applied potential of 1.5 V. Surface morphological, spectroelectrochemical, colorimetric and redox properties of polymer were investigated. Spectroelectrochemical and colorimetry studies have shown that ThFc has green color in neutral state. The reaction of the ferrocenyl dithiophosphonate and nickel(II) acetate gave rise to square-planar nickel(II)complex (ThFc-Ni). ThFc-Ni complex copolymerize with thiophene and spectroelectrochemical properties of copolymer were also investigated. en_US
dc.language.iso en en_US
dc.publisher Elsevier B.V. en_US
dc.relation.ispartof Synthetic Metals en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.subject Boron trifluoride diethyl etherate en_US
dc.subject Conductive Polymers en_US
dc.subject Electrochemical techniques en_US
dc.subject Inorganic-organic hybrid en_US
dc.subject Metallopolymers en_US
dc.subject Spectroelectrochemical analysis en_US
dc.subject Spectroelectrochemical properties en_US
dc.subject Square-planar nickel en_US
dc.subject Electrochemistry en_US
dc.subject Electrochromic materials en_US
dc.subject Electrochromic devices en_US
dc.subject Green colored electrochromic en_US
dc.subject Metal complex en_US
dc.title Ferrocenyl dithiophosphonate functionalized inorganic-organic hybrid conductive polymer with green color in neutral state en_US
dc.type Article en_US
dc.identifier.volume 180 en_US
dc.identifier.startpage 25 en_US
dc.identifier.endpage 31 en_US
dc.authorid 0000-0002-9460-1215
dc.authorid 0000-0002-0000-4613
dc.authorid 0000-0002-0016-019X
dc.identifier.doi 10.1016/j.synthmet.2013.07.017
dc.relation.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
dc.identifier.scopus 2-s2.0-84883261644 en_US
dc.identifier.wos WOS:000325671000004 en_US

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