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The Extraction Ability and Sensitivity of Porphyrazine Derivatives Towards Some Transition Metal Cations

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dc.contributor.author Kabay, Nilgün
dc.contributor.author Baygu, Yasemin
dc.contributor.author Ocak, Ümmühan
dc.contributor.author Gün, Serhat
dc.contributor.author Gök, Yaşar
dc.date.accessioned 2019-08-16T13:11:53Z
dc.date.available 2019-08-16T13:11:53Z
dc.date.issued 2015
dc.identifier.issn 01496395 (ISSN)
dc.identifier.uri http://acikerisim.pau.edu.tr:8080/xmlui/handle/11499/10120
dc.description.abstract The synthesis of novel metal-free and magnesium porphyrazines, peripherally substituted with dithia-dioxa (S2O2) and tetrathia (S4) 14-membered macrocycles were performed by cyclotetramerization of (6Z)-1,3,4,9,10,12-hexahydro-2,5,8,11-benzo-dioxadithiacyclotetradecine-6,7-dicarbodinitrile (3) or (6Z)-1,3,4,9,10,12-hexahydro 2,5,8,11-benzotetrathiacyclotetradecine-6,7-dicarbodinitrile (5). The metal-free porphyrazines have been obtained by known route. The structure of compounds were characterized by elemental analysis and 1H, 13C NMR, IR, UV-vis, and MS spectral data. The solvent extraction properties of the synthesized compounds towards some metal cations, such as Ag(I), Hg(II), Cu(II), Mn(II), Cr(III), Ni(II), Pb(II), and Zn(II) have been investigated. The effect of Cu2+, Mn2+, Ni2+, Pb2+, Sr2+, Al3+, Zn2+, Ba2+, Cd2+, Co2+, Hg2+, and Ag+ ions on the absorption spectra of the compounds were investigated by means of spectrophotometric method. Magnesium porphyrazine with S2O2 (6) interacted within Hg2+ ion specifically of all the tested metal ions. © , Copyright © Taylor & Francis Group, LLC.
dc.language.iso English
dc.publisher Taylor and Francis Inc.
dc.relation.isversionof 10.1080/01496395.2014.978468
dc.rights info:eu-repo/semantics/closedAccess
dc.subject extraction
dc.subject magnesium porphyrazine
dc.subject metal-free porphyrazine
dc.subject mixed donor macrocycle
dc.subject transition metals
dc.subject Chromium compounds
dc.subject Cobalt compounds
dc.subject Copper
dc.subject Extraction
dc.subject Lead
dc.subject Lead compounds
dc.subject Magnesium
dc.subject Manganese
dc.subject Mercury (metal)
dc.subject Metal ions
dc.subject Metals
dc.subject Nickel
dc.subject Positive ions
dc.subject Solvent extraction
dc.subject Spectrophotometry
dc.subject Transition metals
dc.subject Zinc
dc.subject Zinc compounds
dc.subject Cyclotetramerization
dc.subject Extraction properties
dc.subject Macrocycles
dc.subject Metal cation
dc.subject Porphyrazines
dc.subject Spectral data
dc.subject Spectro-photometric method
dc.subject Transition metal cations
dc.subject Cadmium compounds
dc.title The Extraction Ability and Sensitivity of Porphyrazine Derivatives Towards Some Transition Metal Cations
dc.type Article
dc.relation.journal Separation Science and Technology (Philadelphia)
dc.identifier.volume 50
dc.identifier.issue 7
dc.identifier.startpage 1002
dc.identifier.endpage 1009
dc.relation.publicationCategory Uluslararası Hakemli Dergi
dc.identifier.index Scopus
dc.identifier.index WOS

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